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Methodology for Rare Earth Element Determinations of Uranium Oxides by Ion Microprobe

2007· article· en· W2162933590 on OpenAlexaboutno aff
Jessica Bonhoure, Philippe Kister, Michel Cuney, Étienne Deloule

Bibliographic record

VenueGeostandards and Geoanalytical Research · 2007
Typearticle
Languageen
FieldChemistry
TopicRadioactive element chemistry and processing
Canadian institutionsnot available
Fundersnot available
KeywordsUraniumGeologyUranium oreGeochemistryUnconformityMicroprobeVeinCalderaRare-earth elementMineralogyMetallogenyMetamorphic rockMonaziteRare earthVolcanoPyriteMetallurgySedimentary rockZirconSphalerite

Abstract

fetched live from OpenAlex

A methodology for the determination of the rare earth elements in uranium oxides by ion microprobe has been set up on a Cameca ims‐3f instrument. An uranium oxide reference material from a syn‐metamorphic uranium deposit related to albitisation has also been developed for this type of analysis. Applications of the methodology are presented for a series of uranium oxides selected from some major uranium deposit types: from the world's highest grade unconformity‐related uranium deposit from the Athabasca Basin (Saskatchewan, Canada; the Shea Creek and the McArthur River examples), a perigranitic vein‐type deposit (Pen Ar Ran, Vendée, France) and a volcanic caldera‐related deposit (Streltsovkoye, Transbaikalia, Russia). Each type of uranium deposit appears to have a specific REE signature. All REE patterns from the Shea Creek and the McArthur deposits are characterised by bell‐shaped patterns centred on Tb‐Dy and similar to those already published for uranium oxides from unconformity‐related deposits from Australia. Such bell‐shaped REE patterns centred on Tb‐Dy may therefore be considered as a typical signature of uranium oxides from Mesoproterozoic unconformity‐related deposits. A smoother bell shape pattern centred on Eu characterises the syn‐metamorphic albitisation related deposit of Mistamisk selected for the reference material. The REE patterns from the Pen Ar Ran deposit show a fractionation from LREE to HREE with anomalously high abundances of Sm, Eu and Gd with respect to the other REEs, similar to the REE patterns of uranium oxides from the volcanic‐related deposits of Streltsovkoye.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.005
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.151
Threshold uncertainty score0.629

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0050.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.093
GPT teacher head0.432
Teacher spread0.339 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations33
Published2007
Admission routes1
Has abstractyes

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