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Transport of Ions and Solvent Through a Nafion Membrane Modified with Polypyrrole

2012· article· en· W2165325914 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Membrane and Separation Technology · 2012
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsnot available
Fundersnot available
KeywordsPolypyrroleChemistryNafionAmmonium persulfateMembraneAqueous solutionInorganic chemistryPolymerizationElectrodialysisElectrolytePolymerElectrochemistryOrganic chemistryElectrode

Abstract

fetched live from OpenAlex

The Nafion®117 membrane was modified chemically, using a conducting polymer pyrrole. The oxidants ferric chloride (PPy-Fe), hydrogen peroxide (PPy-O) and ammonium persulfate (PPy-S) were used to carry out the polymerization in the membrane both in aqueous and organic media. The Nafion® modified in the presence of the N-méthylformamide increases the transport of alkali and heavy metal cations and reduces considerably the transport of methanol both in diffusion and electro-osmosis. Therefore, the modified Nafion® membrane can be used successfully in electrodialysis of electrolyte solutions in both aqueous and hydro-organic media and may be regarded as a good material to use in Direct Methanol Fuel Cells.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.265

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.224
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it