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Record W2167450294 · doi:10.1002/anie.200250613

In Search of Ruthenium(<scp>II</scp>) Complexes Based on Tridentate Polypyridine Ligands that Feature Long‐lived Room‐Temperature Luminescence: The Multichromophore Approach

2003· article· en· W2167450294 on OpenAlexaff
Rosalba Passalacqua, Frédérique Loiseau, Sebastiano Campagna, Yuan‐Qing Fang, Garry S. Hanan

Bibliographic record

VenueAngewandte Chemie International Edition · 2003
Typearticle
Languageen
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsUniversité de MontréalUniversity of Waterloo
Fundersnot available
KeywordsRutheniumLuminescenceChromophoreChemistryFeature (linguistics)Combinatorial chemistryMetalComputer sciencePhotochemistryMaterials scienceOrganic chemistryOptoelectronicsCatalysisPhilosophy

Abstract

fetched live from OpenAlex

Time trials: A ruthenium(II) complex based on tridentate polypyridine ligands (see picture) featuring the longest luminescence lifetime (1.8 μs) ever reported is described. This new species has been obtained by applying the multichromophore approach, in which the various metal- and organic-based chromophores are only weakly interacting, so that their individual properties are essentially maintained.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.041
GPT teacher head0.282
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations123
Published2003
Admission routes1
Has abstractyes

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