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Record W2170012564 · doi:10.1002/047084289x.rs096

Sodium Periodate-Potassium Permanganate

2001· reference-entry· en· W2170012564 on OpenAlexaff
Andrew G. H. Wee, Baosheng Liu

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2001
Typereference-entry
Languageen
FieldChemical Engineering
TopicAnalytical Chemistry and Sensors
Canadian institutionsUniversity of Regina
Fundersnot available
KeywordsPotassium permanganateChemistryReagentGlass woolSodium periodatePermanganateNuclear chemistryPeriodateWaste managementInorganic chemistryOrganic chemistryEngineering

Abstract

fetched live from OpenAlex

(NaIO4) [7790-28-5] INaO4 (MW 213.89) InChI = 1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 InChIKey = JQWHASGSAFIOCM-UHFFFAOYSA-M (KMnO4) [7722-64-7] KMnO4 (MW 158.04) InChI = 1S/K.Mn.4O/q+1;;;;;-1 InChIKey = VZJVWSHVAAUDKD-UHFFFAOYSA-N (oxidant for the cleavage of carbon–carbon double bonds1) Physical Data: NaIO4: mp 300 °C (dec); specific gravity 3.865. KMnO4: mp 240 °C (dec); specific gravity 2.703. Solubility: NaIO4: sol H2SO4, HNO3, MeCO2H, hot water; slightly sol cold water. KMnO4: sol MeOH, acetone, hot water; slightly sol cold water. Form Supplied in: NaIO4: white to colorless efflorescent solid. KMnO4: dark purple crystals. Both reagents are widely available and can be used as supplied. Handling, Storage, and Precautions: gloves and safety goggles must be worn during handling; avoid inhalation of dust and contact with combustible matter.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.041
Threshold uncertainty score0.138

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0020.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0410.034

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.239
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2001
Admission routes1
Has abstractyes

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