Synthesis, crystal structures and thermal analysis of two new coordination polymers
Bibliographic record
Abstract
Two new silver(I) – dithioether coordination polymers based on the combination of the dithioether ligand L = CH 3 –S(CH 2 ) 3 S–CH 3 and AgX silver salts, where X = NO 3 − (1) and CF 3 CF 2 COO − (2), have been synthesized and characterized. In both coordination polymers, the dithioether building blocks propagated the silver (I) centers to build chains, in which the counteranions complete the coordination sphere of the metal centers. Furthermore, the tubular chains in 2 are, in turn, associated through weak C F … F C interactions into 3D-structures. The thermogravimetric investigation reveals that those complexes decompose in a single step respectively to metallic silver. The stoichiometries of the obtained polymers were found to be dependent of the starting metal-to-ligand ratio.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".