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Record W2175355573 · doi:10.1139/v11-012

Luminescence and decay properties of the <sup>1</sup>D<sub>2</sub> level of Pr<sup>3+</sup>-doped YPO<sub>4</sub>

2011· article· en· W2175355573 on OpenAlexvenueno aff
John Collins, Marco Bettinelli, Baldassare Di Bartolo

Bibliographic record

VenueCanadian Journal of Chemistry · 2011
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence Properties of Advanced Materials
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryLuminescenceDopingRedistribution (election)Radiative transferPopulationAtomic physicsAnalytical Chemistry (journal)Polarization (electrochemistry)Relaxation (psychology)Radioactive decayDopantPhysical chemistryCondensed matter physicsPhysicsOptics

Abstract

fetched live from OpenAlex

This investigation reports on the spectroscopic properties of trivalent Pr in YPO 4 . In particular, we show how the luminescence from the 1 D 2 level depends on the polarization of the emission and on the temperature of the sample. We also report on the decay kinetics of the 1 D 2 level, which show the lifetime decreasing as temperature is increased. Our observed lifetime of 440 µs is at low temperature and is significantly longer than that reported by other workers. We explain the temperature dependence of the 1 D 2 emission by considering the population redistribution in the 1 D 2 level, without invoking the existence of multiphonon relaxation. Finally, we estimate the radiative decay rates of individual crystal field levels within the 1 D 2 manifold.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.002
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.041
GPT teacher head0.206
Teacher spread0.165 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2011
Admission routes1
Has abstractyes

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