Styrene/Methacrylic Acid Monomer Reactivity Ratio Estimation in Bulk and Solution at High Temperatures
Why this work is in the frame
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Bibliographic record
Abstract
Abstract: Styrene/methacrylic acid (Sty/MAA) free radical copolymerizations have been conducted in bulk and in m-xylene solution (60 wt% solvent level) at 100 and 130°C using tert-butyl peroxybenzoate as initiator. Monomer reactivity ratios and their temperature dependence have been determined from low conversion copolymer composition data using the computer software package RREVM, which is based on the error in variables model (EVM) method. It was found that the reactivity ratio values change with dilution by m-xylene from the values obtained in bulk at both temperatures.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it