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Record W2175815970 · doi:10.1002/cjce.22361

Propargyl resin derived from biosynthesized oligophenols for the application of high temperature composite matrix

2015· article· en· W2175815970 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2015
Typearticle
Languageen
FieldEngineering
TopicEpoxy Resin Curing Processes
Canadian institutionsnot available
Fundersnot available
KeywordsDifferential scanning calorimetryMaterials scienceComposite numberComposite materialBenzoyl peroxideExothermic reactionPolymerizationPropargylYield (engineering)Thermal decompositionPolymerCatalysisChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract A novel addition‐cure‐type propargyloligophenol resin for high‐temperature usage was prepared via a two‐step process: Horseradish Peroxidase (HRP) catalyzed oxidation polymerization of phenols to oligophenols, and Williamson etherification of oligophenols to propargyloligophenols. Propargyloligophenols possess an ideal processability for composite manufacture, i.e. good solubility, low melting point (< 50 °C), and thermal curability. As shown by Differential Scanning Calorimetry (DSC), propargyloligophenol resin upon heating experiences a broad thermal exothermic peak in the range of 175–300 °C peaking at around 260 °C. The cured resin is high‐temperature resistant with an initial decomposition temperature > 400 °C and an anaerobic char yield > 60 % at 700 °C. The mechanical properties of glass fabric‐reinforced propargyloligophenol laminate were superior to those of conventional phenolic resins. The results showed that propargyloligophenol resin is a prospective polymeric matrix for high temperature composites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.169
Threshold uncertainty score0.393

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.207
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it