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Record W2176049376 · doi:10.1002/047084289x.rn01617

Palladium(II) Bromide

2013· reference-entry· en· W2176049376 on OpenAlexaff
Stuart J. Mahoney, Éric Fillion

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2013
Typereference-entry
Languageen
FieldMaterials Science
TopicLanthanide and Transition Metal Complexes
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsPalladiumBromideChemistryOrganic chemistryCatalysis

Abstract

fetched live from OpenAlex

[13444-94-5] PdBr2 (MW 266.23) InChI = 1S/2BrH.Pd/h2*1H;/q;;+2/p-2 InChIKey = INIOZDBICVTGEO-UHFFFAOYSA-L (used as an oxidizing agent; used as a Pd(II) catalyst; used as a source of Pd(0) precatalyst) Alternate Names: palladium bromide; palladium dibromide. Physical Data: mp 717 ± 2 °C1; X-ray structure.2 Solubility: soluble in HBr; insoluble in H2O.1 Form Supplied in: commercially available as a dark brown powder. Analysis of Reagent Purity: elemental analysis.3 Preparative Methods: palladium metal with HNO3 and HBr,1, 4 electrosynthesis from palladium metal and HBr,3 and by palladium metal with Br2 at high temperature.1 Handling, Storage, and Precautions: air stable; not hygroscopic.1

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.256
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0350.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.241
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2013
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Reagents for Organic SynthesisSame topicLanthanide and Transition Metal ComplexesFrench-language works237,207