Kinetics of microdomain structures in multi-phase polymer-liquid crystalline materials
Bibliographic record
Abstract
A mesoscopic kinetic model for phase separation in the presence of liquid crystalline order has been formulated, and solved using high performance numerical methods. The thermodynamic phase diagram on temperature-polymer concentration plane indicates the presence of coexistence regions between isotropic and liquid crystalline phases. These regions are itself partition by the phase separation spinodal and the phase ordering spinodal. We characterize the morphologies following temperature quenches in the phase diagram. The scenario is completely different from isotropic mixing since the continuous phase exhibits liquid crystalline ordering. Microdomains of the dispersed phase induce long- and short-range forces affecting the kinetics of the separation and the emerging structures. Presence of topological defects and elastic distortions around the microdomains formed during the phase separation dominate the morphology. The free energy of the system establishes dynamics and correlations of the morphological structures.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".