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Record W2186475725 · doi:10.1139/cjp-2013-0670

Theoretical calculation of the low-lying doublet electronic states of the SrF molecule

2014· article· en· W2186475725 on OpenAlexvenueno aff
F. Jardali, Mahmoud Korek, Ghassan Younes

Bibliographic record

VenueCanadian Journal of Physics · 2014
Typearticle
Languageen
FieldPhysics and Astronomy
TopicCold Atom Physics and Bose-Einstein Condensates
Canadian institutionsnot available
Fundersnot available
KeywordsPhysicsMultireference configuration interactionAtomic physicsDipoleComplete active spaceEigenvalues and eigenvectorsGround stateElectronic structurePotential energyPerturbation theory (quantum mechanics)Configuration interactionQuantum mechanicsMoleculeExcited stateMolecular orbital

Abstract

fetched live from OpenAlex

The potential energy curves of the low-lying doublet electronic states in the representation 2s+1 Λ (+/−) of the SrF molecule have been investigated by using the complete active space self-consistent field with multireference configuration interaction and multireference Rayleigh–Schrödinger perturbation theory methods. The harmonic frequency, ω e ; the internuclear distance, R e ; the dipole moment; and the electronic energy with respect to the ground state, T e , have been calculated for the considered electronic states. The eigenvalues, E v ; the rotational constants, B v ; and the abscissas of the turning points, R min and R max , have been investigated using the canonical functions approach. The comparison between the values of the present work and those available in the literature for several electronic states shows very good agreement. Nine new electronic states have been investigated here for the first time.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.349
Threshold uncertainty score0.278

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.193
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2014
Admission routes1
Has abstractyes

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