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Record W2188242286

SYNTHESIS AND CHARACTERISTICS OF SYNTHESIS AND CHARACTERISTICS OF THIOPHENE BASED MONOAZO DISPERSE DYES ON NYLON 6.6 FABRIC

2014· article· en· W2188242286 on OpenAlex
S M Chindo, I. Y. Chindo, D. E. A. Boryo, K. A. Bello, N. S Gin

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueInternational Journal of Chemistry · 2014
Typearticle
Languageen
FieldEngineering
TopicDyeing and Modifying Textile Fibers
Canadian institutionsnot available
Fundersnot available
KeywordsAnilineChemistryBenzidineThiophenePolymer chemistryAbsorption (acoustics)Absorption spectroscopyNuclear chemistryPhotochemistryOrganic chemistryComposite materialMaterials scienceOptics
DOInot available

Abstract

fetched live from OpenAlex

A series of monoazo disperse dyes has been prepared by diazotizing 2-amino-4(-4chlorophenylcarbamoyl)-5-methyl-thiophene-3- carboxylic acid ethylester and coupling with N, Nbis (2-cynoethyl) aniline, 3-acetylamino-N,N-diethylaniline and 3-hydroxyl-N,N-dimethyl aniline. The monoazo disperse dyes were characterized by infra red spectra studies. Visible absorption spectra of the dyes were examined in various solvents. The electronic absorption spectra covers a λmax range of 550-650 nm at uniformly high absorption intensity between 2.3 × 10 4 - 9.2 × 10 4 l mol -1 cm -1 . These dyes were applied at 5 % depth on nylon 6.6 fabrics and gave bright intense hues of purple and orange. The colour parameters of the dyed fabrics were measured and the dyes have excellent exhaustion between 79-92 % for nylon 6.6 fabrics, more intense and of very good wash fastness property on nylon 6.6 fabrics. The remarkable degree of levelness and brightness after washing is indicative of good penetration and excellent affinity of these dyes for the nylon 6.6 fabric.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.110
Threshold uncertainty score0.527

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.204
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it