Polyoxometalate Complexes as Precursors to Vanadium‐Doped Molybdenum or Tungsten Oxide Thin Films by Means of Aerosol‐Assisted Chemical Vapour Deposition
Why this work is in the frame
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Bibliographic record
Abstract
Abstract Aerosol‐assisted chemical vapour deposition of substituted polyoxometalates H 4 [PMo 11 VO 40 ], H 7 [PMo 8 V 4 O 40 ], [ n Bu 4 N] 4 [PVW 11 O 40 ] and [ n Bu 4 N] 5 [PV 2 W 10 O 40 ] resulted in the formation of vanadium‐doped metal oxide thin films. Depositions were carried out at 550 °C in methanol or acetonitrile for the POMs that contained molybdenum or tungsten, respectively. The as‐deposited films were X‐ray amorphous and relatively non‐adherent. However, on annealing in air at 600 °C, decolourised translucent films that were more mechanically robust were obtained. Films deposited from H 4 [PMo 11 VO 40 ] and H 7 [PMo 8 V 4 O 40 ] consisted of V‐doped MoO 3 in the orthorhombic phase and films from [ n Bu 4 N] 4 [PVW 11 O 40 ] and [ n Bu 4 N] 5 [PV 2 W 10 O 40 ] comprised of monoclinic V‐doped WO 3 . All films were fully characterised by using X‐ray photoelectron spectroscopy, energy‐dispersive X‐ray diffraction, scanning electron microscopy and UV/Vis spectroscopy.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it