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Record W2265237373 · doi:10.1002/ejic.201501063

Thermoelectric Properties of Ni<sub>0.05</sub>Mo<sub>3</sub>Sb<sub>5.4</sub>Te<sub>1.6</sub> with Embedded SiC and Al<sub>2</sub>O<sub>3</sub> Nanoparticles

2016· article· en· W2265237373 on OpenAlexafffund
Nagaraj Nandihalli, Quansheng Guo, Stéphane Gorsse, Atta Ullah Khan, Takao Mori, Holger Kleinke

Bibliographic record

VenueEuropean Journal of Inorganic Chemistry · 2016
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Thermoelectric Materials and Devices
Canadian institutionsUniversity of Waterloo
FundersNational Institute for Materials ScienceNatural Sciences and Engineering Research Council of Canada
KeywordsSpark plasma sinteringThermoelectric effectFigure of meritThermal conductivityVolume fractionAnalytical Chemistry (journal)Hot pressingSeebeck coefficientNanoparticleSinteringChemistryMaterials scienceMetallurgyComposite materialNanotechnologyOptoelectronicsThermodynamicsChromatography

Abstract

fetched live from OpenAlex

Abstract First, a large sample of Ni 0.05 Mo 3 Sb 5.4 Te 1.6 was prepared by heating the elements in the stoichiometric ratio. β‐SiC nanoparticles were added in volume fractions, f , of 0.01, 0.02, and 0.034 to three different portions of the material, and a portion without SiC nanoparticles was retained as a reference. All four samples were subjected to consolidation by hot‐pressing. Furthermore, Al 2 O 3 nanoparticles were added in volume fractions of f = 0.01, 0.0216, and 0.0325 to three other portions, again retaining a fourth protion as reference. These four samples were consolidated by spark‐plasma sintering. The thermoelectric transport properties of these composites were characterized from 325 to 740 K. For the sample with 0.01 volume fraction of SiC, there was an enhancement in figure of merit by 18 % compared with the reference sample, mainly due to an 18 % reduced thermal conductivity. The 9 % reduction in thermal conductivity of the sample with 0.01 volume fraction of Al 2 O 3 was not enough to compensate the loss in the power factor of 18 %, leading to a decrease in the figure of merit. Microstructural information obtained by SEM, TEM, and BET was used to elucidate the phase and transport properties. The spark‐plasma‐sintered bulk sample has a figure of merit that is 35 % higher than the bulk sample consolidated through hot‐pressing.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.032
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.001
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0010.002
Science and technology studies0.0010.001
Scholarly communication0.0010.002
Open science0.0020.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.184
Teacher spread0.177 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2016
Admission routes2
Has abstractyes

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