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Investigation of Relationships between Petroleum Properties and Their Impact on Crude Oil Compatibility

2015· article· en· W2274400296 on OpenAlexfundno aff
Dicho Stratiev, Ivelina Shishkova, Angel Nedelchev, Кiril Кirilov, Ekaterina Nikolaychuk, Atanas Ivanov, Ilshat Sharafutdinov, Anife Veli, Magdalena Mitkova, Tanya Tsaneva, Nedyalka B. Petkova, R.M. Sharpe, Dobromir Yordanov, Zlatozvet Belchev, Svetoslav Nenov, Nikolay A. Rudnev, Vassia Atanassova, Evdokia Sotirova, Sotir Sotirov, Krassimir Atanassov

Bibliographic record

VenueEnergy & Fuels · 2015
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsnot available
FundersArmy Research OfficeBulgarian National Science FundCanadian Institute for Advanced Research
KeywordsAsphalteneSulfurAromaticityChemistryDistillationLight crude oilRefineryNaphthaPetroleumSolubilityKeroseneOrganic chemistryOil refineryFuel oilRefining (metallurgy)SulfideHydrodesulfurizationChemical engineeringWaste managementCatalysis

Abstract

fetched live from OpenAlex

Twenty-two crude oils around the world, from which 19 are processed in the LUKOIL Neftohim Burgas (LNB) refinery, were characterized in the LNB research laboratory by measuring 67 properties. These 22 crude oils included light low sulfur, light sulfur, intermediate low sulfur, intermediate sulfur, intermediate high sulfur, heavy high sulfur, and extra heavy extra high sulfur crudes. A new mathematical approach—the intercriteria analysis—was employed to study the relations between the petroleum properties. It was found that the petroleum properties, density, and sulfur content, along with the crude oil simulated distillation, seem to be capable of providing the same information as that from the full assay of a crude oil. Crude oils containing insoluble asphaltenes (self-incompatible oils) were found to have a high content of low aromaticity naphtha and kerosene. It was found that the asphaltene solubility correlated with the asphaltene hydrogen content. The oil solubility power was found to correlate with the oil saturate content. The oil colloidal stability seems to be controlled by the following rule: “like dissolves like”. The higher the aromaticity of the asphaltenes, the higher the aromaticity of the oil is required to keep the asphaltenes in solution. The processing of blends of oils which are incompatible or nearly incompatible may deteriorate the performance of the dewatering and desalting in the refinery, which consequently may damage the equipment due to accelerated corrosion, entailed by salt deposition. The processing of blends of oils, which are incompatible, not always can be related to an increased fouling.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.534
Threshold uncertainty score0.427

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.080
GPT teacher head0.254
Teacher spread0.174 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations47
Published2015
Admission routes1
Has abstractyes

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