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Record W2277195071 · doi:10.2138/am.2011.3673

Cranswickite MgSO4{middle dot}4H2O, a new mineral from Calingasta, Argentina

2011· article· en· W2277195071 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAmerican Mineralogist · 2011
Typearticle
Languageen
FieldMaterials Science
TopicCrystal Structures and Properties
Canadian institutionsQueen's University
Fundersnot available
KeywordsOctahedronCrystallographyMonoclinic crystal systemMineralPowder diffractionCrystal structureRaman spectroscopyMoleculeChemistryMagnesiumInfrared spectroscopyMaterials sciencePhysics

Abstract

fetched live from OpenAlex

Cranswickite is a newly recognized mineral of composition MgSO4·4H2O from Calingasta, San Juan Province, Argentina (IMA2010-016). Cranswickite is monoclinic, space group C2/c, a = 11.9236(3), b = 5.1736(1), c = 12.1958(3) Å, β = 117.548(2)°, V= 667.0(1) Å3, Z = 4, dobs = 1.917 g/cm3, and dcalc = 1.918 g/cm3. The mineral occurs0 as a soft white vein filling in a metasedimentary rock. The atomic structure has been determined by direct methods and refined by Rietveld analysis of powder diffraction data. The atomic structure consists of chains of corner-sharing magnesium-containing octahedra and sulfate tetrahedra similar to the structure of pentahydrite. All the water molecules directly coordinate magnesium in the structure. The five strongest lines in the powder X-ray diffraction data are [dobs in angstroms (I) (hkl)]: 5.259 (100) (200), 3.927 (46) (112̄), 3.168 (45) (113̄), 4.603 (29) (111̄), 2.570 (23) (311). Infrared and Raman spectra are very similar to the spectra measured from starkeyite. The chemical composition of cranswickite is the same as starkeyite MgSO4·4H2O, but starkeyite has an atomic structure where two sulfate tetrahedra and two Mg(H2O)6 octahedra share corners to form a four-membered ring and not a chain as in cranswickite. The new mineral is named in honor of Lachlan M.D. Cranswick (1968-2010), an Australian crystallographer who helped to developed and maintain the Collaborative Computational Project No. 14 in Powder and Small Molecule Single Crystal Diffraction (CCP14).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.707
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.051
GPT teacher head0.229
Teacher spread0.178 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it