Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Silicone elastomers are normally thermoset materials. While their inherent properties make them highly valuable, it would be of interest to develop stimuli-responsive silicones whose properties could be reversibly tuned at will. In the case of silicone polymers, a particularly interesting trigger is light, since silicone elastomers can readily be formulated to be transparent. We describe the utilization of coumarin-modified silicones for this purpose. On their own, the presence of coumarin groups converts silicone oils into thermoplastic elastomers through physical (noncovalent) cross-linking. UV-irradiation permits covalent cross-linking through [2 + 2] cycloadditions and is accompanied by loss of most physical cross-links. Higher energy photons permit, in part, photoinitiated retro-cycloaddition and a subsequent decrease in covalent cross-link density. It is thus possible to tailor the physical properties of the elastomer to increase and/or decrease the modulus of the elastomer using light and to convert thermoreversible thermoplastics, by degree, into thermosets.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it