Nitroxide‐Mediated Polymerization of n‐Butyl Acrylate and D‐Limonene
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Summary N ‐butyl acrylate and D‐limonene were copolymerized in bulk via nitroxide‐mediated polymerization (NMP) at 115 °C using SG1‐BlocBuilder. Compared to the free‐radical initiation system, the NMP approach resulted in a moderate enhancement to final conversion and slightly higher incorporation of D‐limonene into the copolymer microstructure. The copolymer composition using the NMP approach did not differ significantly from that of the free‐radical method. A mechanism for the NMP of BA/Lim is proposed which includes a degradative chain transfer reaction due to the allylic hydrogen of D‐limonene.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it