Bibliographic record
Abstract
Normal and acid aluminum sulphate solutions containing about 6.0 gr/1 of aluminum and up to 50 gr/1 SO₄⁼ were hydrolyzed until equilibrium was reached in the temperature region 125-250°C. Under the equilibrium conditions the only stable solid phase observed in equilibrium with a liquid phase of various compositions was basic aluminum sulphate with nominal formula 3A1₂0₃..4S0₃.9H₂O. A small portion of the ternary diagrams for the system A1₂O₃-SO₃-H₂O at 225°C and 250°C was constructed. A mixture of aluminum sulphate and other metal sulphates, K₂S0₄, Na₂S0₄, Li₂SO₄, FeSO₄ and CuSO₄ i.e. was hydrolyzed at 225°C in order to find the effect of these salts on hydrolysis. The overall hydrolysis reaction was found to occur according to the chemical equation: 6A1⁺⁺⁺+ 4HS0₄⁻ + 14H₂O ⃗ 3Al₂0₃.4S0₃.9H₂0 + 14H⁺ The equilibrium constants at 125, 150, 175, 200, 225 and 250°C were determined. Finally a mechanism for the hydrolysis of aluminum sulphate was proposed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".