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2‐ 15N Glutamine tracer overestimate rates of Arginine and Citrulline synthesis in healthy adult men

2010· article· en· W2289688493 on OpenAlexafffund
Christopher Tomlinson, Mahroukh Rafii, Ronald O. Ball, Paul Pencharz

Bibliographic record

VenueThe FASEB Journal · 2010
Typearticle
Languageen
FieldNursing
TopicClinical Nutrition and Gastroenterology
Canadian institutionsUniversity of AlbertaHospital for Sick ChildrenUniversity of Toronto
FundersCanadian Institutes of Health Research
KeywordsArginineTransaminationCitrullineGlutamineChemistryMetabolismCis–trans isomerismStereochemistryAmino acidBiochemistry

Abstract

fetched live from OpenAlex

Recent studies have documented transfer of labeled nitrogen from 2–15N glutamine (Gln) to citrulline (Cit) and arginine (Arg) in fasting human adults. Conversely, in neonates we have shown no synthesis of Arg from glutamate. Therefore, we performed a multitracer study with 2‐ 15 N and 1‐ 13 C Gln given enterally to 5 healthy men fed a standardized milkshake diet. There was no difference in plasma enrichments between the two Gln tracers. 1‐ 13 C isomers of Cit and Arg were synthesized from 1‐ 13 C Gln. Three isomers each of Cit and Arg were synthesized from the 2‐ 15 N Gln tracer; 2‐ 15 N, 5‐ 15 N and 2,5 15 N 2 . The enrichments of these isomers of Cit and Arg expressed as atom percent excess are shown in the . Enrichment of Arg and Cit isomers synthesized from 1‐ 13 C and 2‐ 15 N Gln 1–13C 2–15N 5–15N 2,5–15N Cit (%) 1.4 1 2.6 1,2 4.0 2 0.8 Arg (%) 0.14 1 0.4 1 0.8 0.1 Significantly greater enrichment was found of both 5‐ 15 N Arg and Cit compared to 2‐ 15 N isomers 2 , indicating the amino N from Gln is mostly transferred to Arg and Cit by transamination. Similarly, the enrichment of the 1‐ 13 C isomers was significantly less than the 2‐ 15 N isomers 1 suggesting rapid formation of α‐ketoglutarate and recycling of the nitrogen label. Our results show Gln is acting primarily as a nitrogen donor for Arg synthesis and studies using 15 N label overestimate Arg synthesis rates. Grant Funding Source: CIHR

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.316
Teacher spread0.295 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2010
Admission routes2
Has abstractyes

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