Diluent selection for<scp>N</scp>ylon 11 and<scp>N</scp>ylon 12 thermally induced phase separation systems
Bibliographic record
Abstract
ABSTRACT Nylon 11 and Nylon 12 are commercially important polymers due to their unique combination of mechanical strength, chemical resistance, and processability. Products have been prepared from these polymers via thermally induced phase separation (TIPS) for many years. Nevertheless, known diluents for Nylon 11 and 12 pose specific processing problems, and it would be desirable to find a diluent that allows low processing temperatures, has a high flash point, is inexpensive, and exhibits low toxicity. This work investigated a variety of alternative diluents not previously documented in the literature. A fundamental study was also performed to determine which factors are important in selecting a diluent for preparing Nylon liquid–liquid TIPS membranes. The information gathered in this study, including phase diagrams for all feasible systems investigated, will be important in shaping future formulation work for Nylon use in microporous membranes. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 43237.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".