Synthese von Inhaltsstoffen der Amaryllisgewächse und nichtnatürlichen Derivaten
Bibliographic record
Abstract
Abstract Dieser Aufsatz behandelt die Fortschritte bei der Synthese von Amaryllidaceae‐Alkaloiden seit der Veröffentlichung des letzten umfassenden Übersichtsartikels im Jahr 2008. Synthesen der Hauptinhaltsstoffe – Pancratistatin, 7‐Desoxypancratistatin, Narciclasin, Lycoricidin und Lycorin – sowie anderer natürlicher Inhaltsstoffe und nichtnatürlicher Derivate werden vorgestellt, und die biologische Aktivität der nichtnatürlichen Derivate wird diskutiert. Ein Ausblick und weitere Entwicklungen auf dem Gebiet beschließen den Aufsatz. Die Literatur wurde bis Ende August 2015 berücksichtigt.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".