Hydrogen sensing with Pd-coated long-range surface plasmon membrane waveguides
Bibliographic record
Abstract
A low power, reusable optical hydrogen sensor using long-range surface plasmon polariton (LRSPP) cladded membrane waveguides is demonstrated. The sensor incorporates a 5 μm wide, 20 nm thick gold stripe embedded in a 160 nm thick free-standing Cytop membrane with a 5 nm thick Pd over-layer. Input and output coupling is achieved with directly integrated broadside grating couplers. The sensor is tested with hydrogen concentrations up to 3% and demonstrates a strong response with an estimated detection limit of 290 ppm, and a response time of 7 s to a 0.6% H2 step - this level of performance is among the best reported for optical H2 sensors. Cycling of the hydrogen exposure shows a significant hysteresis response, however no film deformation or delamination was observed over many cycles. The high stress that is induced in clamped films during hydrogenation is relaxed in due to the film being deposited on the flexible and elastic Cytop membrane. This could result in improved lifetimes for this sensor and increased uptake ability.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".