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Record W2313458130 · doi:10.1107/s010876730809867x

Theoretical prediction and characterization of high-pressure structures and properties of calcium

2008· article· en· W2313458130 on OpenAlexaff
D. D. Klug, Yingwu Yao, John S. Tse, Jianfei Sun, Y. Le Page

Bibliographic record

VenueActa Crystallographica Section A Foundations of Crystallography · 2008
Typearticle
Languageen
FieldEngineering
TopicEnergetic Materials and Combustion
Canadian institutionsNational Research Council CanadaUniversity of SaskatchewanSteacie Institute for Molecular Sciences
Fundersnot available
KeywordsCharacterization (materials science)CalciumGeologyMaterials scienceNanotechnologyMetallurgy

Abstract

fetched live from OpenAlex

This study employed a combination of theoretical techniques to predict the structure and properties of calcium IV and V at high pressures. Structural predictions for calcium in the pressure range 120-160 GPa were obtained with a genetic algorithm and with a pseudo-random search method. The X-ray diffraction pattern of the resulting structures are in excellent agreement with recent experimental results. Phonon and electron-phonon calculations were performed with plane-wave density functional methods to investigate the stabilities and potential superconductivity. The proposed structures are both found to be superconducting and the calculated Tc values are close to those observed for Ca-IV and V. Theory indicates a superconducting transition at 25 K for the structures obtained in this study, in excellent agreement with experiment. Analysis of a recent theoretically predicted structure indicates that this structure may be unstable at high pressures

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.824
Threshold uncertainty score0.697

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.188
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2008
Admission routes1
Has abstractyes

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