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Record W2317200193 · doi:10.1021/acs.analchem.5b00696

Sourcing of Copper and Lead within Red Inclusions from Trinitite Postdetonation Material

2015· article· en· W2317200193 on OpenAlexaboutno aff
Elizabeth C. Koeman, Antonio Simonetti, Peter C. Burns

Bibliographic record

VenueAnalytical Chemistry · 2015
Typearticle
Languageen
FieldEngineering
TopicMetal Extraction and Bioleaching
Canadian institutionsnot available
FundersNotre Dame Integrated Imaging Facility, University of Notre DameNational Nuclear Security Administration
KeywordsChemistryCopperLead (geology)MetallurgyGeologyOrganic chemistry

Abstract

fetched live from OpenAlex

Historical postdetonation materials resulting from nuclear testing can be used to develop methodologies for source attribution, in particular if the chemical and isotopic signatures of the device are public domain. The samples analyzed in this study are from the world's first nuclear bomb explosion in 1945, the Trinity Test, and produced the postdetonation material "Trinitite". The latter is a glassy material that resulted from the melting of the natural sand present at ground zero (Alamogordo, NM) and incorporated components of the device. Chemical and isotopic (e.g., Pu) information on the device is declassified and, therefore, methodologies for fingerprinting fuel and other device components can be verified. One type of Trinitite contains red inclusions that are characterized by high concentrations of Pb (between 438 and 26,631 μg/g) and Cu (between 404 and 22,280 μg/g) that are in general positively correlated. Pb isotope compositions for the red inclusion areas exhibit a large variation and indicate mixing between Pb from at least 3 different sources: 1- natural geological background (arkosic sand) present at ground zero; 2- anthropogenic component from the device; and 3- industrial Cu used for wiring in the device. Based on the Pb isotope ratios for the red inclusions within Trinitite, it is likely that the anthropogenic Pb derives from Buchans Mine (Newfoundland, Canada), which is in agreement with a previous investigation. Products of industrial Cu manufacturing (e.g., pennies) were analyzed for their trace element abundances and Pb isotope compositions; these suggest that Cu employed within the device's wiring was derived from two Cu ore deposits within the USA.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.160
Threshold uncertainty score0.262

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.246
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2015
Admission routes1
Has abstractyes

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