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Record W2317567110 · doi:10.1021/ef502534w

Effective Method To Determine Supersaturation of Tar Balls Deposited along the Caspian Sea

2015· article· en· W2317567110 on OpenAlexaff
Javad Sayyad Amin, Somayye Nikkhah, Sohrab Zendehboudi, Lesley James

Bibliographic record

VenueEnergy & Fuels · 2015
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsSupersaturationMetastabilityPrecipitationtar (computing)SolventMaterials scienceChemistryMineralogyEnvironmental scienceThermodynamicsMeteorologyPhysics

Abstract

fetched live from OpenAlex

The south coast of the Caspian Sea is being faced with oil pollution because of intensive petroleum activities in the region. Stranded tar balls on the beaches are considered as one of the evidence for oil pollution. In this study, the supersaturation of tar balls, which are collected from Caspian Sea beaches, is investigated using the anti-solvent precipitation technique. The scope of this research is the metastable zone width limit and its influence on supersaturation. Supersaturation is measured for precipitated tar ball particles within a n -hexane/methanol mixture. In general, supersaturation acts as a driving force for tar ball precipitation when the anti-solvent is added. Response surface methodology is used to evaluate the influences of vital parameters, such as anti-solvent addition rate, mixing regime, initial solute concentration, and metastable zone, on the supersaturation phenomenon, leading toward obtaining a statistical model to forecast supersaturation. In comparison of the response surface model predictions to the experimental data, a very good accuracy is noticed. Moreover, the analysis of variance (ANOVA) technique is employed to evaluate validity of the proposed model, implying that the metastability zone width has the most important effect on the supersaturation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0020.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.260
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2015
Admission routes1
Has abstractyes

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