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Record W2317821931 · doi:10.1149/1.3701968

Nanostructured Thin Film Electrocatalysts for PEM Fuel Cells - A Tutorial on the Fundamental Characteristics and Practical Properties of NSTF Catalysts

2012· article· en· W2317821931 on OpenAlexfundno aff
Mark K. Debe

Bibliographic record

VenueECS Transactions · 2012
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsnot available
FundersArgonne National LaboratoryOffice of Energy EfficiencyOffice of Energy Efficiency and Renewable EnergyDalhousie UniversityU.S. Department of Energy
KeywordsElectrocatalystAnodeCathodeProton exchange membrane fuel cellFuel cellsMaterials scienceNanotechnologyDurabilityCatalysisThin filmComputer scienceElectrodeChemical engineeringComposite materialChemistryElectrical engineeringEngineeringElectrochemistry

Abstract

fetched live from OpenAlex

This tutorial reviews the key aspects and literature to date around the nanostructured thin film (NSTF) electrocatalyst technology platform for PEM fuel cells and electrolyzers. The NSTF technology is to date the only practical example of an extended surface area catalyst shown to effectively address several of the performance, cost and durability barriers facing cathode and anode catalysts for fuel cell vehicles. The unique physical characteristics of these ultra-thin, low Pt-loaded electrodes also require alternative solutions for water management and impurity tolerance. We present an overview of the NSTF electrocatalysts' four primary differentiating features, to show how their material and basic geometric and material characteristics translate to functional performance factors. We conclude by briefly recounting the historical origins of the NSTF material with the recommendation that the field of ordered organic molecular solids represents a large opportunity for developing tailored support materials for heterogeneous catalysis.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: none
Teacher disagreement score0.002
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.230
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations99
Published2012
Admission routes1
Has abstractyes

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Same venueECS TransactionsSame topicElectrocatalysts for Energy ConversionFrench-language works237,207