Pressure-Dependent Luminescence Properties of Gold(I) and Silver(I) Dithiocarbamate Compounds
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Bibliographic record
Abstract
Luminescence spectra for dithiocarbamate complexes of gold(I) and silver(I) display very different luminescence properties. At room temperature, a narrow band with a maximum at approximately 18 000 cm –1 and a broad band with a maximum at approximately 13 000 cm –1 are observed for the gold(I) and silver(I) compounds, respectively. The luminescence from the gold(I) compounds is strongly affected by external pressure, with maxima shifting to lower energy by approximately −120 cm –1 /kbar. In contrast, a silver compound shows a small shift to higher energy by approximately +20 cm –1 /kbar. These shifts are analyzed in terms of structure and bridging ligand geometry, revealing the important influence of unsupported metal–metal interactions on pressure-induced shifts of luminescence bands.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it