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Record W2319103697 · doi:10.1021/je500274r

Physicochemical Characterization of Anionic and Cationic Microemulsions: Water Solubilization, Particle Size Distribution, Surface Tension, and Structural Parameters

2014· article· en· W2319103697 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2014
Typearticle
Languageen
FieldChemistry
TopicSurfactants and Colloidal Systems
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsMicroemulsionChemistryPulmonary surfactantSurface tensionDynamic light scatteringDodecaneAqueous solutionChemical engineeringParticle sizeCationic polymerizationMicelleDilutionChromatographyOrganic chemistryNanoparticleThermodynamicsPhysical chemistry

Abstract

fetched live from OpenAlex

The composition, oil type, and thermodynamic parameters influence the water solubilization capacity, particle size distribution, surface tension, and also the structural parameters of microemulsion systems. In the present study sodium lauryl sulfate (SLS) and hexadecyltrimethylammonium bromide (HTAB) have been used as surfactants and 3-methyl-1-butanol as cosurfactant to prepare microemulsions. Four n -alkanes (hexane, heptane, decane, and dodecane) were chosen as oil phases. Water solubilization capacities of anionic (SLS) and cationic (HTAB) microemulsions were investigated in both the presence and the absence of NaCl salt. A detailed study of particle size analysis for both the surfactants with different composition has been made from laser light scattering measurement. Surface tensions of microemulsions and surfactant solutions were also measured for investigation of their surface activities. Surface tensions have been reduced remarkably in the case of microemulsion systems compared to simple aqueous solutions of surfactants. Different structural parameters like water droplet and effective microemulsion droplet size including interface, aggregation numbers of surfactant, and cosurfactant have been determined assuming monodispersity of the droplets from dilution experiment. The effects of temperature on the above parameters have also been studied.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.041
Threshold uncertainty score0.398

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.212
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it