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Record W2319659504 · doi:10.1021/jp412662x

Dewetting Dynamics of a Solid Microsphere by Emulsion Drops

2014· article· en· W2319659504 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2014
Typearticle
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsDewettingContact angleMaterials scienceOil dropletMicroscale chemistryEmulsionWettingAqueous solutionChemical engineeringRheologyNanotechnologyComposite materialChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

A novel micropipet technique was developed to quantify the dewetting dynamics of individual microsphere particles by emulsified viscous crude oil drops in aqueous media. This technique allowed dynamic microscale receding contact angles of water to be measured in situ for solid–oil–water systems. System parameters, including modification of glass microspheres and characteristics of oil drops, were varied to study their effect on dewetting dynamics of the systems. Increasing solvent dosage in viscous oil was found to decrease static receding contact angle of water for clean and bitumen-treated glass surfaces, but showed a negligible effect on static receding contact angle for ethyl cellulose (EC)-treated glass surface. Interestingly, dynamic dewetting behavior exhibited a strong dependence on surface modification and the addition of solvent to viscous oil. No dewetting dynamics was observed for clean hydrophilic glass surface. For bitumen- or EC-treated glass surfaces, more rapid dewetting dynamics of water were determined with increasing addition of solvent to viscous oil. Both de Gennes viscous dissipation hydrodynamic and the Blake/Haynes molecular-kinetic models were developed for the current system to understand the observed dynamic dewetting characteristics.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.016
Threshold uncertainty score0.220

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.236
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it