The significance of buried landscape in subsurface migration of dense non-aqueous phase liquids; the case of perchloroethylene in the Sussex Aquifer, New Brunswick
Bibliographic record
Abstract
Abstract At Sussex, New Brunswick, dissolved perchloroethylene (PCE) as high as 28.0 mu g/liter, was detected within the upper aquifer and in concentrations to 1.6 mu g/liter within the lower aquifer that serves as the main source of municipal water supply. Predominantly formed as an esker ridge, the lower aquifer consists of well-sorted, glaciofluvial/ice-contact, sand and gravel layers mostly confined by underlying till and/or bedrock and an overlying unit of laminated silt-clay glaciolacustrine sediments (middle aquitard). The middle aquitard is in turn overlain by an upper aquifer of variable thickness, extending from a depth of about 18 m to near surface, consisting of coarsening-upward sand and gravel, with occasional lenses of clay, silt and diamicton. A dispersal plume was identified by contouring PCE concentrations from 72 samples from the upper aquifer; PCE was not detected in 16 surface soil samples. The highest concentrations imply that the PCE originated from a surface spill near the urban business center and that subsurface migration was influenced significantly by a buried relict river channel cut into the middle aquitard. Scouring along the channel bottom cut through the middle aquitard and intersected the esker ridge of the underlying water supply aquifer, forming windows through the aquitard. Contamination of the lower aquifer has likely originated from the PCE being drawn through these windows during pumping of a water-supply well that is now out of service. Results indicate that withdrawal rates and placement of original municipal water wells, as well as the stratigraphy, conductivity and topography of subsurface units are controlling factors in Dense Non-Aqueous Phase Liquid migration at this site.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".