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Record W2320030457 · doi:10.1021/ie501029u

Copper Exchanged Nanotitanate for High Temperature H<sub>2</sub>S Adsorption

2014· article· en· W2320030457 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2014
Typearticle
Languageen
FieldEngineering
TopicIndustrial Gas Emission Control
Canadian institutionsUniversity of Alberta
FundersHelmholtz-Alberta Initiative
KeywordsAdsorptionCopperAtmospheric temperature rangeChemistryDissociation (chemistry)Materials scienceChemical engineeringThermodynamicsPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

The H 2 S breakthrough capacity of copper-exchanged Engelhard Titanosilicate-2 (ETS-2) was measured at temperatures up to 950 °C and it was found that the adsorbent efficiency remains unchanged across the entire temperature range. Below 750 °C, the adsorption capacity at breakthrough is 0.7 mol of H 2 S per mole of copper while above 750 °C the capacity of the adsorbent is halved. The change in H 2 S capacity is due to Cu 2+ reduction by the H 2 which is formed through the thermal dissociation of H 2 S. The adsorbent shows good potential for use over a wide range of operating temperatures in H 2 S scrubbing processes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.002
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.042
GPT teacher head0.271
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it