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Record W2320337719 · doi:10.1021/ef401790n

Transesterification of Triglyceride to Fatty Acid Alkyl Esters (Biodiesel): Comparison of Utility Requirements and Capital Costs between Reaction Separation and Catalytic Distillation Configurations

2013· article· en· W2320337719 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnergy & Fuels · 2013
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaConselho Nacional de Desenvolvimento Científico e Tecnológico
KeywordsBiodieselBiodiesel productionTransesterificationGallon (US)Raw materialDistillationCapital costWaste managementReactive distillationBiofuelEnvironmental scienceProcess engineeringPulp and paper industryEngineeringChemistryMethanolCatalysisOrganic chemistry

Abstract

fetched live from OpenAlex

The efficacy of catalytic distillation (CD) and the economic merits that it would bring into the biodiesel production process is studied. Process flow sheets depicting conventional and CD technology are modeled in Aspen Plus, and detailed operating conditions and equipment designs are provided for each process. The feedstock considered is soybean oil, and the transesterification reaction for the triglyceride is considered for biodiesel production. After optimal design of both process flow sheets to produce 10 million gallons of biodiesel per year, adhering to ASTM purity standards, a detailed cost analysis is carried out using the Aspen economic analyzer tool to predict capital, operating, and utility costs and to calculate the cost of production per gallon of biodiesel. Results depict CD to be a promising candidate to replicate the conversion and product purity of conventional biodiesel processes while having significant savings in capital (41.42% cheaper than the conventional process) and utility (18.12% less than the conventional process) costs, thereby making it a very competitive alternative. The total operating costs and price of production per gallon of biodiesel are only meagerly cheaper for a CD process because the most significant factor to the biodiesel production process is the raw material cost. For both processes, the price of production per gallon of biodiesel after accounting for revenue generated from glycerol product is predicted to be around 1.7 dollars/gallon. The Aspen model is flexible to accommodate higher flow rates for scale-up of operations, add or remove stages of operation into the biodiesel process, modify feedstock and stream prices, and predict associated capital and production costs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.261
Threshold uncertainty score0.541

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.035
GPT teacher head0.285
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it