Integrative Synthesis of Coordination Polymers, Metal Oxides, and Alloys Magnetic Nanoparticles in MSU Mesoporous Silica
Bibliographic record
Abstract
Metal cyanobridged coordination polymers—or Prussian blue analogues (PBA)—nanoparticles have been synthesized along with a mesostructured MSU-type silica matrix. This synthesis was applied to several M (II) 3 [M′ (III) (CN) 6 ] 2, (M = Co, Ni, Fe; M′ = Co, Fe) and a homogeneous distribution of PBA nanometric particles was obtained, even at high concentration (>20 wt %) within a silica matrix that exhibits long-range order as the result of the concomitant increase in concentration of nonionic surfactants templates during the synthesis. The same magnetic behavior as observed for bulk materials was observed with the magnetic PBA nanoparticles and thermal treatment under different atmospheres leads to the formation of bimetallic oxides or alloys, which display magnetic properties.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".