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Record W2321799794 · doi:10.1166/jnn.2012.6778

Graphite Nanoplatelets Produced by Oxidation and Thermal Exfoliation of Graphite and Electrical Conductivities of Their Epoxy Composites

2012· article· en· W2321799794 on OpenAlex
Mohsin Ali Raza, Aidan Westwood, Andy Brown, Nicole Hondow, Chris Stirling

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Nanoscience and Nanotechnology · 2012
Typearticle
Languageen
FieldEngineering
TopicFiber-reinforced polymer composites
Canadian institutionsnot available
FundersEngineering and Physical Sciences Research Council
KeywordsGraphiteMaterials scienceExfoliation jointComposite materialIntercalation (chemistry)Percolation thresholdGraphite oxideExfoliated graphite nano-plateletsEpoxyGrapheneElectrical resistivity and conductivityNanotechnology

Abstract

fetched live from OpenAlex

Graphite nanoplatelets were produced by sonication of thermally reduced graphite oxide produced from three precursor graphites. The thicknesses of the resulting graphite nanoplatlets were measured by X-ray diffraction and transmission electron microscopy. The type and size of the precursor graphite plays an important role in the final graphite nanoplatelet quality. The thinnest graphite nanoplatelets (average thickness of 4-7 nm) were obtained from Sri Lankan powdered graphite (average particle size of 0.1-0.2 mm). Thicker graphite nanoplatelets (average thickness of 30-60 nm), were obtained from a Canadian graphite (with an average flake size of 0.5-2 mm). Graphite nanoplatelets obtained by acid intercalation of Sri Lankan graphite were much thicker (an average thickness of 150 nm). Graphite nanoplatelet/epoxy composites containing 4 wt.% graphite nanoplatelets derived from Canadian or Sri Lankan natural graphite have electrical conductivities significantly above the percolation conductivity threshold. In contrast, corresponding composites, produced with (4 wt.%) commercial graphite nanoplatelets, either as-received or re-exfoliated, were electrically insulating. This behaviour is attributed to the highly wrinkled morphology, folded edges and abundant surface functional groups of the commercial graphite nanoplatelets. Thermal reduction of graphite oxide produced from natural flake graphite is therefore a promising route for producing graphite nanoplatelets fillers for electrically-conducting polymer composites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.012
Threshold uncertainty score0.412

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.183
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it