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Record W2321875386 · doi:10.1021/ic302505p

Slow Magnetization Relaxation in Unprecedented Mn<sup>III</sup><sub>4</sub>Dy<sup>III</sup><sub>3</sub> and Mn<sup>III</sup><sub>4</sub>Dy<sup>III</sup><sub>5</sub> Clusters from the Use of <i>N</i>-Salicylidene-<i>o</i>-aminophenol

2013· article· en· W2321875386 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueInorganic Chemistry · 2013
Typearticle
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsBrock University
FundersOntario Trillium Foundation
KeywordsChemistryMagnetizationStoichiometryManganeseRelaxation (psychology)CrystallographyDysprosiumMetalPhase (matter)Analytical Chemistry (journal)Physical chemistryInorganic chemistryPhysicsMagnetic field

Abstract

fetched live from OpenAlex

The first use of N-salicylidene-o-aminophenol in 3d/4f chemistry has led to Mn(III)(4)Dy(III)(5) and Mn(III)(4)Dy(III)(3) clusters with unprecedented metal topologies and stoichiometries; both compounds exhibit out-of-phase signals indicative of the slow magnetization relaxation of a single-molecule magnet.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.050
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.004
Meta-epidemiology (narrow)0.0040.004
Meta-epidemiology (broad)0.0040.001
Bibliometrics0.0010.005
Science and technology studies0.0020.003
Scholarly communication0.0030.005
Open science0.0050.003
Research integrity0.0030.003
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.208
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it