Fast Lithium-Ion Conducting Garnet-Like Electrolytes for Potential Application in Lithium Ion Batteries
Bibliographic record
Abstract
In this paper, we report the effect of Y-doping for Nb in the garnet-like Li5La3Nb2O12 on Li-ion conductivity. The phase formation, microstructure and electrical conductivity studies were done using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), 7Li nuclear magnetic resonance (Li-NMR) and AC impedance spectroscopy. The formation of cubic garnet-like structure was observed for x up to 0.25 and additional impurity peaks were observed above x = 0.25 in Li5La3Nb2-xYxO12-δ. 7Li MAS NMR exhibits a single peak close to a chemical shift value of 0 ppm with respect to LiCl which could be due to the fast conduction of Li ions. Lithium ion conductivity of 1.34 x 10-5 and 1.44 x 10-5 Scm-1 was observed for x = 0.05 and 0.1 members, respectively at 23 °C in air.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".