Chemical Bonding and Hybridization in 5<i>p</i> Binary Oxide
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
We analyze the electronic structure of several 5 p binary oxides (In 2 O 3, SnO, SnO 2, Sb 2 O 3, Sb 2 O 5, and TeO 2 ) using density functional theory and soft X-ray spectroscopy. We find that there is bonding in hybridized cation 5 s -O 2 p states at the bottom of the valence band in oxides with cations in both the formal 5 s 2 and 5 s 0 valencies. We similarly find that there is antibonding in hybridized cation 5 d - or 5 s -O 2 p states at the top of the valence band for oxides with cations in 5 s 2 or 5 s 0 valencies, respectively, and the density of O 2 p states in these antibonding states is much greater in the 5 s 0 oxides than the 5 s 2 oxides. The calculated and quasi-empirical band gaps for these oxides are tabulated, and we identify the hybridizations responsible for the spectral features in the measured XES.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it