Analytical Impedance Model for Electrochemically Driven Conducting Polymer Devices
Bibliographic record
Abstract
An analytical model is presented to describe the electrochemical impedance of conducting polymer based devices. The analytical expression of the impedance is obtained from a two dimensional finite transmission line equivalent circuit. The model relates impedance to cell geometry, electrolyte conductivity, polymer ionic and electronic conductivities and capacitance. These parameters were measured for a hexafluorophosphate (PF6-) doped polypyrrole material (the conducting polymer used in this study) and entered to the model to predict its impedance as a function of frequency. The model is unique in representing the two dimensional charging of the polymer, namely ionic mass transport through the thickness of the polymer structure and electronic resistance along its length. Close agreement is observed between impedance spectroscopy results and model prections of the charging of a polypyrrole film electrically connected at one end. The provides a means of modeling the electrochemical charging of conducting polymers and electrochemical double layer capacitor electrodes having significant ionic and electronic conductivities.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.004 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".