MétaCan
Menu
Back to cohort
Record W2324240374 · doi:10.1021/je990332n

Viscometric Constants for Sodium Polystyrene Sulfonate Standards in Solvents of 0.1 M CH<sub>3</sub>COOH/0.2 M NaCl and 0.2 M CH<sub>3</sub>COOH/0.1 M CH<sub>3</sub>COONa at 25.0 °C

2000· article· en· W2324240374 on OpenAlexaff
Johnathan Z. Knaul, Van Tam Bui, Katherine A. M. Creber

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2000
Typearticle
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsRoyal Military College of Canada
Fundersnot available
KeywordsChemistryAqueous solutionSolventPolystyreneSulfonateSodiumViscometerPhase (matter)Analytical Chemistry (journal)Ubbelohde viscometerChromatographyPhysical chemistryViscosityOrganic chemistryIntrinsic viscosityPolymerThermodynamics

Abstract

fetched live from OpenAlex

The viscometric or Mark−Houwink constants K and a for sodium polystyrene sulfonate (NaPSS) standards in two different aqueous solvents (0.1 M CH 3 COOH/0.2 M NaCl and 0.2 M CH 3 COOH/0.1 M CH 3 COONa) were determined at 25.0 °C using a Ubbelohde viscometer. They are 3.288 × 10 - 3 mL·g - 1 and 1.908 × 10 - 3 mL·g - 1 for K and 0.788 and 0.851 for a for the above two solvent systems, respectively. These constants were then used for establishing the universal calibration relationship for a size exclusion chromatography column using the above two aqueous solvents as the mobile phase.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0020.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.238
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2000
Admission routes1
Has abstractyes

Explore more

Same venueJournal of Chemical & Engineering DataSame topicAnalytical Chemistry and ChromatographyFrench-language works237,207