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Record W2324798939 · doi:10.1021/es4009486

Constraints on Carbon Monoxide Emissions Based on Tall Tower Measurements in the U.S. Upper Midwest

2013· article· en· W2324798939 on OpenAlexaff
Su Youn Kim, Dylan B. Millet, Lu Hu, Michael Möhr, Timothy J. Griffis, Deyong Wen, John C. Lin, Scot M. Miller, Marcos Longo

Bibliographic record

VenueEnvironmental Science & Technology · 2013
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsUniversity of Waterloo
FundersNational Eye InstituteUniversity of MinnesotaU.S. Environmental Protection AgencyNational Science Foundation
KeywordsEmission inventoryEnvironmental scienceCarbon monoxideSensitivity (control systems)Atmospheric sciencesA priori and a posterioriTowerLagrangianMeteorologyBiomass (ecology)Dispersion (optics)Range (aeronautics)MathematicsChemistryAir quality indexGeographyPhysicsEngineeringGeologyApplied mathematics

Abstract

fetched live from OpenAlex

We interpret a full year of high-frequency CO measurements from a tall tower in the U.S. Upper Midwest with a time-reversed Lagrangian Particle Dispersion Model (STILT LPDM) and an Eulerian chemical transport model (GEOS-Chem CTM) to develop top-down constraints on U.S. CO sources in 2009. Our best estimate is that anthropogenic CO emissions in the U.S. Upper Midwest in 2009 were 2.9 Tg, 61% lower (a posteriori scale factor of 0.39) than our a priori prediction based on the U.S. EPA's National Emission Inventory for 2005 (NEI 2005). If the same bias applies across the contiguous U.S., the inferred CO emissions are 26 Tg/y, compared to the a priori estimate of 66 Tg/y. This discrepancy is significantly greater than would be expected based solely on emission decreases between 2005 and 2009 (EPA estimate: 23% decrease). Model transport error is an important source of uncertainty in the analysis, and we employ an ensemble of sensitivity runs using multiple meteorological data sets and model configurations to assess its impact on our results. A posteriori scale factors for the U.S. anthropogenic CO source from these sensitivity runs range from 0.22 to 0.64, corresponding to emissions of 1.6-4.8 Tg/y for the U.S. Upper Midwest and 15-42 Tg/y for the contiguous U.S. The data have limited sensitivity for constraining biomass + biofuel burning emissions and photochemical CO production from precursor organic compounds. Our finding of a NEI 2005 overestimate of CO emissions is consistent with recent assessments for individual cities and with earlier analyses based on the NEI 1999, implying the need for a better mechanism for refining such bottom-up emission estimates in response to top-down constraints.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.004
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.300
Threshold uncertainty score0.596

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.004
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.002
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.196
Teacher spread0.185 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations40
Published2013
Admission routes1
Has abstractyes

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