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Record W2326494589 · doi:10.1021/jz401508t

Get the Basics Right: Jacobian Conversion of Wavelength and Energy Scales for Quantitative Analysis of Emission Spectra

2013· article· en· W2326494589 on OpenAlexaffabout
Jonathan Mooney, Patanjali Kambhampati

Bibliographic record

VenueThe Journal of Physical Chemistry Letters · 2013
Typearticle
Languageen
FieldChemistry
TopicElectrochemical Analysis and Applications
Canadian institutionsMcGill University
Fundersnot available
KeywordsNoticeAltmetricsCitationEnergy (signal processing)Computer scienceLibrary scienceMathematicsStatisticsPolitical scienceLaw

Abstract

fetched live from OpenAlex

E ffective representation of data plays a vital role in scientific communication.Moreover, a different representation of the same raw data may facilitate better quantitative analysis.Often, signal data are recorded and presented as a function of the electromagnetic spectrum.Commonly, spectra are recorded in wavelength units, but presentation of data as a function of energy provides better physical insight.The inverse relationship between the two quantities presents some challenges and has sometimes led to incorrect conclusions, such as the assertion that the spectral response of the human eye is optimized to match the solar spectrum.Clearly, proper presentation of spectral data is critical for enlightening scientific investigation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.017
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.615
Threshold uncertainty score0.549

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.017
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0010.002
Bibliometrics0.0050.003
Science and technology studies0.0010.001
Scholarly communication0.0040.006
Open science0.0020.003
Research integrity0.0020.004
Insufficient payload (model declined to judge)0.6150.422

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.228
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designTheoretical or conceptual
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations426
Published2013
Admission routes2
Has abstractyes

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