Platinum-Catalyzed Alkene Cyclohydroamination: Evaluating the Utility of Bidentate P,N/P,P Ligation and Phosphine-Free Catalyst Systems
Bibliographic record
Abstract
The efficacy of phosphine-free Pt precatalysts including PtCl 2 and (COD)PtCl 2 in promoting the cyclohydroamination of primary as well as secondary alkyl/arylamines tethered to α-olefins is demonstrated for the first time. Further catalytic studies examining the use of phenylene-P,N co-ligands, as well as neutral, cationic, and formally zwitterionic complexes derived from the new ligand precursor 1-PPh 2 -2-P(tBu) 2 -indene, revealed comparable reactivity in Pt-catalyzed cyclohydroamination catalysis relative to these phosphine-free catalysts.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".