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Record W2326642977 · doi:10.1002/chem.201490122

Cover Picture: Silicon Meets Cyclotron: Muon Spin Resonance of Organosilicon Radicals / The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity / Enantioselective Construction of Quaternary Stereogenic Carbon Atoms by the Lewis Base Catalyzed Additions of Silyl Ketene Imines to Aldehydes / Iron Silicates, Iron‐Modulated Zeolite Catalysts, and Molecular Models Thereof / Ultrathin Silica Films: The Atomic Structure of Two‐Dimensional Crystals and Glasses / Preparation of a Sulfo‐Group‐Containing Rod‐Like Polysilsesquioxane with a Hexagonally Stacked Structure and Its Proton Conductivity / [2+2+1] Cycloadditions of Bis(dialkylamino)acetylenes with SiI<sub>2</sub>(Idip): Syntheses and Reactivity Studies of Unprecedented 2,3,4,5‐Tetraamino‐1 <i>H</i>‐siloles / Dynamic Complexation of Copper(I) Chloride by Carbene‐Stabilized Disilicon (Chem. Eur. J. 30/2014)

2014· paratext· en· W2326642977 on OpenAlexaff
Robert West, Kerim Samedov, Paul W. Percival, Peter Jutzi, Scott E. Denmark, Tyler W. Wilson, Matthew T. Burk, Denise Pinkert, Christian Limberg, Christin Büchner, Leonid Lichtenstein, Xin Yu, J. Anibal Boscoboinik, Bing Yang, William E. Kaden, Markus Heyde, Shamil Shaikhutdinov, Radosław Włodarczyk, Marek Sierka, Joachim Sauer, Hans‐Joachim Freund, Yoshirō Kaneko, Hisaya Toyodome, Tomonobu Mizumo, Kazuhiro Shikinaka, Nobuo Iyi, Yury Lebedev, Ujjal Das, Oleg Chernov, Gregor Schnakenburg, Alexander C. Filippou, Mingwei Chen, Yuzhong Wang, Yaoming Xie, Pingrong Wei, Robert J. Gilliard, Nichole A. Schwartz, Henry F. Schaefer, Paul von Ragué Schleyer, Gregory H. Robinson

Bibliographic record

VenueChemistry - A European Journal · 2014
Typeparatext
Languageen
FieldChemistry
TopicZeolite Catalysis and Synthesis
Canadian institutionsSimon Fraser UniversityTRIUMF
Fundersnot available
KeywordsSiliconMuon spin spectroscopyCrystallographyOrganosiliconReactivity (psychology)ChemistryLewis acids and basesElectron paramagnetic resonanceCatalysisStereochemistryMuonPhysicsPolymer chemistryNuclear magnetic resonanceNuclear physicsOrganic chemistry

Abstract

fetched live from OpenAlex

The cover picture highlights eight of the papers published in this themed issue, specially put together for the 17th International Symposium on Silicon Chemistry. In the top row from left to right: R. West et al. (p. 9184 ff.), P. Jutzi (p. 9192 ff.), and S. E. Denmark et al. (p. 9268 ff.). In the middle row: left C. Limberg and D. Pinkert (p. 9166 ff.) and right H.-J. Freund et al. (p. 9176 ff.). In the bottom row from left to right: Y. Kaneko et al. (p. 9394 ff.), A. Filippou et al. (p. 9280 ff.), and G. H. Robinson et al. (p. 9208 ff.). The range of papers reflects how silicon chemistry can provide a platform for synergistic solutions through novel method developments of synthetic and analytical tools and the interconnection of different disciplines in molecular and materials chemistry.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.273
Threshold uncertainty score0.913

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.2730.049

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.226
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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Same venueChemistry - A European JournalSame topicZeolite Catalysis and SynthesisFrench-language works237,207