Surfactant-Free Switchable Emulsions Using CO<sub>2</sub>-Responsive Particles
Bibliographic record
Abstract
Surfactant-free emulsions are prepared using bi-wetting particles which occupy the oil-water interface to effectively reduce the oil-water interfacial area. The equilibrium position of the particle at the interface is determined by its wettability. CO2-reponsive chemical functional groups are grafted onto the surface of silica particles. Particles with only CO2-switchable functional groups are capable of stabilizing oil-in-water emulsions. Particles prepared with both CO2-responsive and hydrophobic chemical functional groups on its surface are capable of stabilizing water-in-oil emulsions. Emulsion stability is disturbed when the wettability of the stabilizing particle is altered by introducing CO2 gas to the biphasic mixture, leading to phase separation of emulsions prepared using the functionalized particles. The emulsion stability can be re-established by the removal of CO2 through air sparging. The presence of CO2 imposes positive surface charge to the responsive particles, increasing wettability and, consequently, the ability of the particles to destabilize emulsions.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".