Electrogenerated Chemiluminescence of Monodisperse Au<sub>144</sub>(SC<sub>2</sub>H<sub>4</sub>Ph)<sub>60</sub> Clusters
Why this work is in the frame
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Bibliographic record
Abstract
The electrogenerated chemiluminescence (ECL) of monodispersed Au 144 (SC 2 H 4 Ph) 60 is reported for the first time. Near-infrared ECL of the clusters with a peak wavelength of 930 nm was observed with tri- n -propylamine as the coreactant. On the basis of the energetics and spooling photoluminescence spectroscopy of the various charged species produced via in situ preparative electrolysis, the ECL is consistent with emission from the electrogenerated excited states Au 144 4+ * and Au 144 5+ *.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.001 | 0.002 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.002 | 0.001 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it