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Record W2328041006 · doi:10.1149/1.3112733

Structure and Electrochemical Hydrogen Storage Properties of Mg-Ti Based Materials Prepared by Mechanical Alloying

2009· article· en· W2328041006 on OpenAlexaff
Steeve Rousselot, Marie‐Pierre Bichat, Daniel Guay, Lionel Roué

Bibliographic record

VenueECS Transactions · 2009
Typearticle
Languageen
FieldMaterials Science
TopicHydrogen Storage and Materials
Canadian institutionsInstitut National de la Recherche Scientifique
Fundersnot available
KeywordsHydrogen storageRietveld refinementMaterials scienceElectrochemistryBall millElectrolyteHydrogenCrystal structureDiffractionLattice constantChemical engineeringPowder diffractionAnalytical Chemistry (journal)AlloyCrystallographyMetallurgyPhysical chemistryChemistryElectrodeOrganic chemistry

Abstract

fetched live from OpenAlex

High energy ball milling was used to prepare Mg100-xTix -10 wt.% Pd compounds, with x ranging from 20 to 80. X-ray diffraction analyses combined with Rietveld refinement shows that the as-milled compounds are made of a mixture of hcp and bcc phases in various proportions depending on the Mg/Ti ratio in the initial mixture. The electrochemical hydrogen absorption capacities of these compounds were assessed in KOH electrolyte. The number of activation cycles and the maximum discharge capacity value are strongly dependant on the material composition. The highest hydrogen discharge capacity (475 mAh g-1) is obtained with Mg50Ti50-10 wt.% Pd compound. Upon hydrogenation, the crystalline structure of the compound evolves into an fcc phase with a lattice parameter of 4.40 Aå.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.213
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2009
Admission routes1
Has abstractyes

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