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Record W2330429066 · doi:10.1002/cjce.22503

Performance of Cu/TiO<sub>2</sub>‐SiO<sub>2</sub> catalysts in hydrogenation of furfural to furfuryl alcohol

2016· article· en· W2330429066 on OpenAlexvenueno aff
Feng Li, Bo Cao, Rui Ma, Jinrong Liang, Hualin Song, Hua Song

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2016
Typearticle
Languageen
FieldEngineering
TopicCatalysis for Biomass Conversion
Canadian institutionsnot available
FundersNortheast Petroleum UniversityNational Natural Science Foundation of China
KeywordsFurfuryl alcoholFurfuralCatalysisX-ray photoelectron spectroscopyMaterials scienceDispersityHydrothermal circulationChemical engineeringNuclear chemistryInorganic chemistryChemistryOrganic chemistryPolymer chemistry

Abstract

fetched live from OpenAlex

Abstract A series of Cu/TiO2‐SiO2 catalysts were prepared by a sol‐gel hydrothermal method and characterized by BET, SEM, TEM, XRD, XPS, and H2‐TPR. The catalysts were used for selective hydrogenation of furfural to furfuryl alcohol. Results show that based on the Cu/SiO2 catalyst, introducing a part of TiO2 into the carrier while keeping very large specific surface area would promote the reduction of CuO, inhibit the growth of Cu crystal particles, and improve the dispersity of Cu particles in the catalyst. The electronegativity of Cu is enhanced in the double‐loaded Cu/TiO2‐SiO2 catalyst, compared with single‐loaded Cu/SiO2 or Cu/TiO2 catalysts. The Cu/TiO2‐SiO2 catalyst containing 0.40 g/g (40 wt%) TiO2 in the carrier shows high furfural hydrogenation performance.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.170
Teacher spread0.164 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations47
Published2016
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian Journal of Chemical EngineeringSame topicCatalysis for Biomass ConversionFrench-language works237,207