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Record W2330537598 · doi:10.1021/jf503704r

Screening for Sulfate in Distillers Dried Grains and Solubles by FT–IR Spectroscopy

2014· article· en· W2330537598 on OpenAlexaboutno aff
Thorben Nietner, M. Pfister, Barbara Brakowiecka-Sassy, Marcus A. Glomb, Carsten Fauhl‐Hassek

Bibliographic record

VenueJournal of Agricultural and Food Chemistry · 2014
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicNitrogen and Sulfur Effects on Brassica
Canadian institutionsnot available
FundersEuropean Commission
KeywordsSulfurSulfateSulfuric acidChemistryFood scienceInorganic chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Distillers Dried Grains and Solubles (DDGS) are an animal feed containing varying levels of sulfur. As ruminants are susceptible to high sulfur diets, sulfur content is of major interest to the parties involved. The variation in levels of sulfur in DDGS is mainly due to sulfate derived from the addition of sulfuric acid during the production. ATR/FT-IR spectroscopy was used to determine sulfate levels in 90 DDGS samples from various origins (Canada, China, EU, and U.S.A.). Specific absorption bands for sulfate at 615 and 1107 cm(-1) enabled the analysis of sulfate in the DDGS matrix. Besides direct quantification (using band at 615 cm(-1)), PLS regression was applied for the prediction of sulfate using FT-IR spectra and calibration with reference values analyzed by capillary electrophoresis. An extended calculation on the total sulfur estimated that 11% of the DDGS samples analyzed in this study featured sulfur contents higher than 0.80%.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.207
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2014
Admission routes1
Has abstractyes

Explore more

Same venueJournal of Agricultural and Food ChemistrySame topicNitrogen and Sulfur Effects on BrassicaFrench-language works237,207