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Record W2333325175 · doi:10.1107/s0108767308098693

Application of a high-pressure CO<sub>2</sub>cell to time-resolved studies with a laboratory powder diffractometer

2008· article· en· W2333325175 on OpenAlexaff
Pamela S. Whitfield, Laura Mitchell, A. Victoria Nawaby, Isobel Davidson

Bibliographic record

VenueActa Crystallographica Section A Foundations of Crystallography · 2008
Typearticle
Languageen
FieldMaterials Science
TopicX-ray Diffraction in Crystallography
Canadian institutionsNational Research Council Canada
Fundersnot available
KeywordsDiffractometerPowder DiffractometerMaterials scienceHigh pressureNuclear engineeringCrystallographyChemistryPhysicsComposite materialEngineering physicsOpticsEngineeringDiffractionScanning electron microscope

Abstract

fetched live from OpenAlex

Microsymposia catalytic material under operative conditions. To recreate actual conditions in a catalytic reactor, and to be able to study many catalytic processes, require a robust and flexible system. We have developed a facility at the Swiss-Norwegian beam lines (SNBL) at the European Synchrotron radiation Facility (ESRF), where operating (flow) conditions up to 20 atm. and 900C in variable and switchable gas mixtures may be achieved. The system will be used for in situ powder diffraction as well as for XAS studies. A mass spectrometer is available for analysis of exhaust gases and a Raman spectrometer has been installed for combined in situ experiments. Results from studies of catalytic materials at operating conditions will be given.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.437
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0040.007
Science and technology studies0.0010.002
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.249
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2008
Admission routes1
Has abstractyes

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